Fast – there's no doubting that. Mercedes claims that the E-class will sprint from 0-62mph in just 5.2sec and reach a limited top speed of 155mph.
What's interesting though is that the nature of the 329bhp 3.0-litre V6 doesn't necessarily correlate with what you might expect. Instead of offering a vast surge of torque from low speed – which is what the figures suggest, stating 325lb ft from 1400-4000rpm – it instead prefers to rev, and rev hard.
Above 4000rpm the V6 really gets into its stride, pushing on eagerly to around the 6400rpm mark. It sounds good too, emitting a refined but purposeful growl when the throttle's pinned, but its delivery feels at odds with the E-class's substantial nature.
Mercedes' seven-speed automatic gearbox does a serviceable job around town but when pressing on, or when prompted via the wheel-mounted paddles for a quick change, it can pause for an uncomfortable duration while it decides what it wants to do next.
This, coupled with the engine's seeming lack of outright low-down torque, means rapid acceleration often requires a committed and lengthy application of throttle. Consequently overtakes may require a little more consideration than they would in something with a V8 or a dual-clutch transmission.
Enthusiasts may further be frustrated to find the Mercedes' stability systems to be overly intrusive. Accelerate sharply out of a junction, or happen to put one driven wheel onto a slick surface while accelerating, and – besides an annoying audible warning – the E 400's power is cut aggressively, resulting in an unpleasant jolt through the car.
While it's understandable that the manufacturer would prefer people kept on the straight and narrow, instead of pirouetting across the road, others manage to stabilise their cars without such pronounced and aggressive intrusion.
Hard acceleration also sees the Benz's economy tumble; our test car returned an indicated 20mpg during the road test and photoshoot, although it's likely that a figure nearer 30mpg should be attainable by most in everyday driving. A standard stop-start system, which operates promptly and without fuss, should help improve the Mercedes' fuel consumption for those who commute in heavy traffic regularly.
Through corners the E 400 proves suitably capable, with masses of front-end grip and good body control. There's plenty of traction on offer too and the substantial brakes bleed off speed with ease; the net result is a car in which it's easy to carry significant speed across country.
Only the steering lets the Mercedes down on the handling front. While accurate, allowing you to place the car on the road with ease, it frequently feels leaden and lacking in consistent weighting. At higher speeds, and with everything in 'Sport' mode, the AMG Sport Plus does feel considerably more composed and rewarding to drive, but suitable roads – and speed limits – are few and far between.
As you might expect, the Mercedes' more aggressive nature has predictably compromised its ride quality and refinement. Even with the dampers in 'Comfort' mode bumps and cracks in the road are transmitted into the cabin with a dull thud, and the Mercedes patters over broken surfaces. There's a notable amount of road noise on some surfaces too, although wind noise is pleasingly low.
While the exterior looks notably more modern than the previous generation, the interior still closely resembles that of the pre-facelift 2009 version and is distinctly lagging behind the likes of the new S-class. There's plenty of kit on offer but some of the finishing, for example the leather-trimmed dashboard that does little to conceal the integrated airbag, leaves much to be desired for such a costly car.
There are some notable ergonomic flaws too; front occupants get plenty of head- and legroom but the driver will find that the E-class's oversized seat bolsters jam against their elbows when applying any notable amount of lock – an obtrusive and annoying flaw. Furthermore, it makes finding a comfortable driving position difficult. Bumps can occasionally result in the odd bit of plastic rattling around too, although that particular fault may be unique to our test car.
Despite the car's long wheelbase rear passenger room isn't particularly good, which may disappoint those looking for a practical coupé. Legroom is barely adequate, with taller occupants' knees regularly being pressed up against the hard plastic backs of the front seats.
Anyone near or in excess of six feet tall will also have to adjust a slouched and uncomfortable seating position in order to avoid clashing with the roof; consequently adults will only want to endure short trips in the rear of the Mercedes.
It's not all bad news on the interior front, however. Visibility is good and the E400 is easy to manoeuvre, while the long doors aren't excessively heavy and access to the rear seats is both quick and effortless.
The Mercedes' boot is of a suitably adequate size too and will easily accommodate large cases. Mercedes quotes 450 litres of storage space, which is five litres larger than BMW's dimensionally similar 4-series coupé.
Mercedes also equips the E 400 as standard with a spacesaver spare wheel, negating any concerns about suffering a puncture and then having to deal with the oft-useless tyre repair kits.